Petroleum Refinery Engineering

Name: _____________________

Date: _____________________

Instructions: Answer all questions. Write your answers clearly in the space provided.

Question 1:

Operating temperature and pressure in catalytic reforming is about

A. 1 - 5 kgf/cm 2 & 200°C
B. 15 - 45 kgf/cm 2 & 450 - 550°C
C. 50 - 75 kgf/cm 2 & 600 - 800°C
D. 5 - 10 kgf/cm 2 & 150 - 250°C
Answer: _________
Question 2:

Pick out the wrong statement.

A. Alkylation produces a larger iso-paraffin (having higher octane number) from the reaction of an olefin with smaller iso-paraffin
B. Catalytic alkylation processes use HF, AlCl 3 & H 2 SO 4 as Catalysts
C. All the alkylation processes use very high temperature (> 1000°C)
D. Gasoline having an octane number of 90 can be produced by alkylation process
E. A pale color of petroleum product indicates lower viscosity
F. Color of petroleum products indicates the degree of refinement
G. Lighter petroleum distillates are lighter in color than the heavier residual oils
H. Flouroscene of oils helps to detect its adulteration
I. Multigrade lubricating oils have high viscosity index
J. Paraffinic oil has very high viscosity index
K. Naphthenic oil has very low viscosity index
L. High viscosity index means a large change in viscosity with change in temperature
M. Aromatics have higher specific gravity than paraffins
N. Gross calorific value (GCV) of petrofuels is equal to (12400 - 2100 ρ 2 ) where, ρ is the specific gravity of the fuel at 15.5°C
O. Heavier petrofuels have higher GCV on weight basis (i.e., Kcal/kg) but lower GCV on volume basis (i.e., Kcal/litre)
P. Higher specific gravity of petrofuels means higher C/H ratio
Q. Higher temperature is employed in visbreaking than in thermal cracking
R. Pyrolysis is a mild thermal cracking process
S. Lead suceptibility of petrol produced by catalytic process is more than that produced by thermal cracking
T. Operating pressure and temperature in thermal cracking process is more than that in catalytic cracking process
U. Lower boiling paraffins have higher octane number than higher paraffins
V. Dehydrogenation of naphthenes to aromatics is a desirable reaction in reforming process
W. The most ideal feedstock for thermal reforming is dearomatised kerosene
X. Catalyst used in catalytic reforming is platinum on silica-alumina base
Y. Pensky-Marten apparatus is used for determining flash points above 50°C
Z. Characterisation factor of paraffinic crude oil is more than 12
[. Abel apparatus is used for determining flash points below 50°C
\. An oil having high susceptibility to change in viscosity with temperature changes, has a high viscosity index
]. Higher specific gravity of petroleum products means higher C/H ratio
^. Aromatics have lower specific gravity than corresponding paraffins
_. Hydrocarbons of low specific gravity (e.g, paraffins) possess the maximum thermal energy per unit volume
`. Hydrocarbons of high specific gravity (eg, aromatics) possess the maximum thermal energy per unit weight
a. Iso-paraffin crack faster than n-paraf-fin
b. Catalytic cracking is endothermic, but the regeneration of catalyst is exothermic
c. Rate of decomposition of olefins in catalytic cracking is slightly slower than the thermal cracking
d. None of these
Answer: _________
Question 3:

Carbon percentage (by weight) in crude petroleum may be about

A. 65
B. 75
C. 85
D. 95
Answer: _________
Question 4:

Hydrogen percentage (by weight) in crude petroleum may be about

A. 5
B. 15
C. 25
D. 35
Answer: _________
Question 5:

Products drawn from the top to bottom of the crude oil distillation column has progressively increasing

A. Boiling points
B. Molecular weight
C. C/H ratio
D. All of the above
Answer: _________
Question 6:

In catalytic cracking process, olefins crack __________ times faster than in thermal cracking process.

A. 100
B. 200-300
C. 1000-10000
D. 10
Answer: _________
Question 7:

Ethyl mercaptan is a/an __________ compound.

A. Sulphur
B. Nitrogen
C. Oxygen
D. None of these
Answer: _________
Question 8:

Lane and Garton classification of petroleum is based on its

A. Composition
B. Specific gravity
C. Optical properties
D. Viscosity
Answer: _________
Question 9:

The main reaction in reforming is the

A. Dehydrogenation of naphthenes
B. Hydrogenation of naphthenes
C. Hydrocracking of paraffins
D. Saturation of olefins
Answer: _________
Question 10:

Petroleum is believed to have originated from __________ sources.

A. Vegetable
B. Animal
C. Both A & B
D. Neither A nor B
Answer: _________
Question 11:

Molecular weight of crude oil is in the range of

A. 100-120
B. 230-250
C. 450-550
D. 600-850
Answer: _________
Question 12:

Octane number of gasoline is a measure of its

A. Resistance to knock
B. Ignition delay
C. Ignition temperature
D. Smoke point
Answer: _________
Question 13:

In petroleum refining, the process used for conversion of hydrocarbons to aromatics is

A. Catalytic cracking
B. Catalytic reforming
C. Hydrotreating
D. Alkylation
Answer: _________
Question 14:

Illuminating characteristics of kerosene is expressed by its

A. Smoke point
B. Aniline point
C. Luminosity number
D. Aromatic content
Answer: _________
Question 15:

Increase in the specific gravity of petroleum products indicates

A. Decrease in paraffin content
B. Increase in thermal energy per unit weight
C. Increase in aromatic content
D. Higher H/C ratio
Answer: _________
Question 16:

The condesate obtained on compression of wet natural gas is termed as

A. Liquefied natural gasoline
B. Natural gasoline
C. Liquid natural gas
D. None of these
Answer: _________
Question 17:

An upper limit of oil content is limited to about __________ percent for achieving efficient and satisfactory level of wax sweating.

A. 5
B. 15
C. 40
D. 60
Answer: _________
Question 18:

The pressure (kg/cm 2 ) and temperature (°C) maintained in electrical desalters for crude oil are respectively

A. 10 and 120
B. 1 and 200
C. 50 and 250
D. 10 and 300
Answer: _________
Question 19:

Which of the following has the highest gum forming tendency in gosoline?

A. Paraffins
B. Diolefins
C. Aromatics
D. Naphthenes
Answer: _________
Question 20:

Highest quality bitumen is produced from the __________ crude oil.

A. Paraffinic
B. Naphthenic
C. Intermediate
D. Mixed
Answer: _________
Question 21:

Butadiene is a/an

A. Di-olefin
B. Naphthene
C. Aromatic
D. Olefin
Answer: _________
Question 22:

Both asphalt and wax are produced by __________ base crude oils.

A. Naphthenic
B. Asphalt
C. Paraffin
D. Mixed
Answer: _________
Question 23:

Paraffins are desirable in lubricating oil, as it has got high

A. Viscosity
B. Viscosity index
C. Smoke point
D. Pour point
Answer: _________
Question 24:

Extractor temperature is maintained at -20°C in Edeleanu process to reduce the __________ of kerosene.

A. Smoke point
B. Paraffins
C. Aromatics
D. Naphthenes
Answer: _________
Question 25:

Petroleum coke is commercially produced by the __________ process.

A. Hydrocracking
B. Visbreaking
C. Fluid catalytic cracking
D. Delayed coking
Answer: _________
Question 26:

Road grade bitumen is produced from vacuum residue by its

A. Aeration
B. Pyrolysis
C. Hydrogenation
D. Steam reforming
Answer: _________
Question 27:

Visbreaking process is used mainly for making

A. High cetane diesel
B. High octane gasoline
C. Fuel oil
D. Smoke free kerosene
Answer: _________
Question 28:

Research octane number refers to the

A. Low octane number motor fuels
B. High octane number motor fuels
C. High octane number aviation fuels
D. Unleaded motor fuels
Answer: _________
Question 29:

Choose the correct statement.

A. Octane number of i-octane is zero
B. Octane number of paraffins increases with increasing number of carbon atoms
C. Branched chain paraffins have higher octane number than straight chain paraffins with same number of carbon atoms
D. The aromatics have lower octane number than naphthenes with same number of carbon atoms
E. Coking tendency increases with increasing molecular weight
F. Coking tendency decreases with increasing molecular weight
G. Higher pressure enhances coke formation
H. Coking is an exothermic reaction
Answer: _________
Question 30:

Which of the following is used as a catalyst in fluidised bed catalytic cracking?

A. Silica-magnesia
B. Silica-alumina
C. Bentonite clays
D. All of the above
Answer: _________
Question 31:

Operating condition in the electrical dehydrators for crude oil is about

A. 6.5 kgf/cm 2 & 95°C
B. 1 atm & 110°C
C. 20 kgf/cm 2 & 110°C
D. 50 atm and 150°C
Answer: _________
Question 32:

Flash point of diesel/kerosene (>50°C) is determined by the

A. Abel apparatus
B. Pensky-Martens apparatus
C. Saybolt chromometer
D. None of these
Answer: _________
Question 33:

Which of the following has the highest flash point of all?

A. Diesel
B. Kerosene
C. Petrol
D. Furnace oil
Answer: _________
Question 34:

Detergent is added as an additive in engine lubricating oil to

A. Reduce deposit formation
B. Keep contaminants in suspension
C. Increase oxidation stability
D. Prevent rusting
Answer: _________
Question 35:

Quinoline is a/an __________ compound.

A. Sulphur
B. Nitrogen
C. Oxygen
D. None of these
Answer: _________
Question 36:

Which of the following has the maximum °API gravity of all?

A. Diesel
B. Kerosene
C. Petrol
D. Furnace oil
Answer: _________
Question 37:

Flash point of motor gasoline may be around __________ °C.

A. 10
B. 45
C. 100
D. 150
Answer: _________
Question 38:

Smoke point of a good burning kerosene may be around __________ mm.

A. 0-5
B. 20-25
C. 60-75
D. 100-120
Answer: _________
Question 39:

Which of the following has the minimum °API gravity of all?

A. Diesel
B. Kerosene
C. Petrol
D. Furnace oil
Answer: _________
Question 40:

'Solvent naphtha' used mostly as a solvent in paints and perfumery is produced by the __________ of virgin naphtha into small boiling range cuts.

A. Steam reforming
B. Distillation
C. Desulphurisation
D. None of these
Answer: _________
Question 41:

Crude oil is subjected to vacuum distillation in the last stage, because

A. High boiling point products like heavy fuel oil & lubricating oils are heat sensitive and may decompose
B. Lighter/low boiling products are prone to thermal decomposition
C. High purity products can be obtained thereby
D. None of these
Answer: _________
Question 42:

Stabilisation of gasoline (petrol) means

A. Removal of dissolved gases from it
B. Increasing its oxidation stability
C. Improving its lead susceptibility
D. Increasing its vapour pressure
Answer: _________
Question 43:

Which is the most undesirable component in kerosene?

A. Aromatics
B. I-paraffins
C. N-paraffins
D. Naphthenes
Answer: _________
Question 44:

Octane number (unleaded) of gasoline produced by isomerisation of butane may be about

A. 45
B. 55
C. 70
D. 90
Answer: _________
Question 45:

With increase in density, the viscosity of petroleum products

A. Increases
B. Decreases
C. Remains same
D. Either A or B
Answer: _________
Question 46:

Viscosity index of a lubricating oil

A. Is the measure of its flash point
B. Is the measure of variation of viscosity with temperature
C. Should be low
D. None of these
Answer: _________
Question 47:

The most commonly used feed stock for the reforming reactor is

A. Heavy fuel oil
B. Residuum
C. Straight run gasdine
D. Casing head gasoline
Answer: _________
Question 48:

With increase in the molecular weight of aromatic present in kerosene, its smoking tendency

A. Increases
B. Decreases
C. Remains same
D. Is unpredictable
Answer: _________
Question 49:

Clay treatment of petroleum products

A. Decolorises & stabilises cracked gasoline
B. Desulphurise straight run gasoline & kerosene
C. Adsorb arsenic from feedstock to catalytic reforming
D. All of the above
Answer: _________
Question 50:

Which one is preferred for aircraft engine?

A. High viscosity index lube oil
B. Low viscosity index lube oil
C. High freezing point aviation fuel
D. None of these
Answer: _________
Question 51:

Reforming

A. Uses naphtha as feedstock
B. Does not much affect the molecular weight of the feed
C. Improves the quality & yield of gasoline
D. All of the above
Answer: _________
Question 52:

Reforming converts

A. Olefins into paraffins
B. Naphthenes into aromatics
C. Naphthenes into olefins
D. Naphthenes into paraffin
Answer: _________
Question 53:

Crude oils containing more than __________ kg of total salts (expressed in terms of NaCl) per thousand barrel is called a 'salty crude'.

A. 1
B. 5
C. 15
D. 25
Answer: _________
Question 54:

Presence of sulphur in gasoline

A. Leads to corrosion
B. Increases lead susceptibility
C. Decreases gum formation
D. Helps during stabilisation
Answer: _________
Question 55:

Which of the following constituents present in petroleum is responsible for ash formation?

A. Nitrogen compounds
B. Organometallic compounds
C. Sulphur compounds
D. Oxygen compounds
Answer: _________
Question 56:

Higher viscosity of lubricating oil usually signifies

A. Lower Reid vapour pressure
B. Higher acid number
C. Higher flash point and fire point
D. Lower flash point and fire point
Answer: _________
Question 57:

The most widely used crude topping column in refineries is the __________ column.

A. Bubble-cap
B. Packed bed
C. Fluidised bed
D. Perforated plate
Answer: _________
Question 58:

Which of the following factors does not govern the mechanism of petroleum formation from organic sources?

A. PH of the soil
B. Bacterial action
C. Heat
D. Pressure
Answer: _________
Question 59:

Feedstock for polymerisation is

A. Naphtha
B. Cracked gases rich in C 2 & C 4 olefins
C. Low boiling aromatics
D. None of these
Answer: _________
Question 60:

The first crude oil refinery of India is located at

A. Naharkatiya
B. Digboi
C. Kochin
D. Madras
Answer: _________
Question 61:

High aniline point of a petrofuel (say diesel) indicates that

A. It is highly aromatic in nature
B. It is highly paraffinic in nature
C. It has a very low diesel index
D. Its ignition quality is very poor
Answer: _________
Question 62:

Aniline point of high speed diesel may be about __________ °C.

A. 35
B. 70
C. 105
D. 150
Answer: _________
Question 63:

In a refinery petroleum crude is fractionated into gas fraction, light ends, intermediate distillates, heavy distillates, residues and by products. The group of products including gas oil, diesel oil and heavy fuel oil belongs to the fraction

A. Heavy distillates
B. Intermediate distillates
C. Light ends
D. Residues
Answer: _________
Question 64:

Cetane number of diesel used in trucks may be about

A. 50
B. 14
C. 35
D. 85
Answer: _________
Question 65:

Higher boiling fractions like atmospheric residue is distilled under vacuum at low temperature because at high temperature, there is a tendency of the predominance of

A. Thermal cracking
B. Gum formation
C. Coking
D. Discoloration
Answer: _________
Question 66:

Doctor's solution used for sweetening of petroleum products is

A. Sodium plumbite
B. Sodium sulphite
C. Sodium thiosulphate
D. Lead sulphate
Answer: _________
Question 67:

Phenols are added in gasoline to

A. Improve the octane number
B. Act as an antioxidant
C. Reduce its viscosity
D. Increase its pour point
Answer: _________
Question 68:

The octane number of aviation gasoline may be

A. 79
B. 87
C. 97
D. >100
Answer: _________
Question 69:

The best method of determining sulphur in crude oil is by the __________ method.

A. Kjeldah
B. Duma
C. Bomb calorimeter
D. Junkar's calorimeter
Answer: _________
Question 70:

Tetra-ethyl lead is added in gasoline to

A. Increase its smoke point
B. Reduce gum formation
C. Reduce the pour point
D. Increase its octane number
Answer: _________
Question 71:

Main boring diameter for petroleum well is 20-30 cms in diameter, while the depth of the oil well may be about __________ kms.

A. 0.1 to 0.5
B. 1.5 to 4.5
C. 7.5 to 12.5
D. 15-20
Answer: _________
Question 72:

Cetane number of alpha methyl naphthalene is assumed to be

A. 0
B. 100
C. 50
D.
Answer: _________
Question 73:

Liquefied petroleum Gas (LPG) used for the household cooking comprises mainly of

A. Propane & butane
B. Butane & ethane
C. Methane & ethane
D. Methane & carbon monoxide
Answer: _________
Question 74:

Crude petroleum oil is a __________ fuel.

A. Primary
B. Fossil
C. Both A & B
D. Secondary
Answer: _________
Question 75:

In hydrofining catalytic desulphurisation process for sweetening of petroleum products, use of hydrogen

A. Enhances the desulphurisation process
B. Minimises coke formation
C. Both A & B
D. Neither A nor B
Answer: _________
Question 76:

95% (by volume) of LPG at 760 mm Hg pressure will evaporate at __________ °C.

A. 2
B. -40
C. 30
D. 55
Answer: _________
Question 77:

Sulphur content in lighter and heavier petroleum products is generally determined respectively by

A. Lamp method and bomb method
B. Bomb method and lamp method
C. Bomb method and quartz tube method
D. Quartz tube method and lamp method
Answer: _________
Question 78:

LPG stands for

A. Liquid petroleum gas
B. Liquified petrol gas
C. Liquid petrol gas
D. Liquefied petroleum gas
Answer: _________
Question 79:

Which of the following reactions is undesirable in the production of catalytically reformed gasoline?

A. Dehydrogenation of naphthene
B. Dehydrogenation of lower paraffins
C. Dehydrocyclisation of higher paraffins
D. Isomerisation of paraffins
Answer: _________
Question 80:

Aniline point is the

A. Characteristic property of diesel & lubricating oils
B. Measure of aromatic content of oil
C. Both A & B
D. Neither A nor B
Answer: _________
Question 81:

Which is the most ideal feed stock for 'coking' process used for the manufacture of petroleum coke?

A. Naphtha
B. Vacuum residue
C. Light gas oil
D. Diesel
Answer: _________
Question 82:

Which of the following has the highest octane number?

A. Aromatics
B. I-paraffins
C. Naphthenes
D. Olefins
Answer: _________
Question 83:

Asphalts are

A. Low molecular weight & low boiling point compounds present in petroleum
B. Desirable in catalytic cracking feedstock, because they produce coke
C. Readily oxidisable and form carbonaceous sludge
D. All of the above
Answer: _________
Question 84:

Which one of the following processes aims at producing higher yield of gaseous unsaturated hydrocarbons and aromatics like benzene & toluene?

A. Reforming
B. Pyrolysis
C. Alkylation
D. Hydrocracking
Answer: _________
Question 85:

Water content in the crude oil as it comes out of oil well may be upto __________ percent.

A. 2
B. 5
C. 10
D. 25
Answer: _________
Question 86:

Clay treatment is used to remove

A. Salt from the crude oil
B. Colour & dissolved gases from cracked gasoline
C. Wax from lube oil
D. None of these
Answer: _________
Question 87:

Pick out the correct statement about catalytic polymerisation.

A. H 2 SO 4 polymerisation process gives gasoline rich in unsaturates
B. In H 2 SO 4 polymerisation, H 3 PO 4 is always used with 2% steam to prevent meta & ortho H 3 PO 4 formation, which are inactive
C. Both A & B
D. Neither A nor B
Answer: _________
Question 88:

Preheating temperature of medium viscosity furnace oil for better atomisation through burner is about __________ °C.

A. 50
B. 70
C. 90
D. 140
Answer: _________
Question 89:

A multigrade lubricating oil means an oil having high

A. Viscosity index
B. Viscosity
C. Aniline point
D. Flash point
Answer: _________
Question 90:

Reid vapour pressure of gasoline is the measure of its

A. Pour point
B. Cloud point
C. Vapour locking tendency
D. Carbon residue
Answer: _________
Question 91:

Which of the following has maximum hydrogen/carbon ratio (by weight)?

A. Naphtha
B. Gasoline
C. Diesel
D. Fuel oil
Answer: _________
Question 92:

Waxy crudes are treated with chemical additives mainly to

A. Depress its pour point
B. Dissolve wax
C. Precipitate wax
D. Remove wax
Answer: _________
Question 93:

Catalyst used in catalytic polymerisation which produces polymer gasoline is

A. H 2 SO 4
B. H 3 PO 4
C. Both A & B
D. AlCl 3
Answer: _________
Question 94:

Diesel used in naval applications has a minimum cetane number of

A. 25
B. 35
C. 45
D. 65
Answer: _________
Question 95:

Which of the following hydrocarbons of same carbon atoms has minimum smoking tendency?

A. Paraffins
B. Naphthenes
C. Aromatics
D. Iso-paraffins
Answer: _________
Question 96:

Which of the following has the lowest cetane number?

A. Aromatics
B. I-paraffins
C. Naphthene
D. Olefins
Answer: _________
Question 97:

Catalyst used in the catalytic polymerisation is

A. Phosphoric acid on kieselghur
B. Aluminium chloride
C. Nickel
D. Vanadium pentaoxide
Answer: _________
Question 98:

Which parameter is used for the grading of paraffin waxes?

A. Specific gravity
B. Melting point
C. Viscosity
D. Penetration number
Answer: _________
Question 99:

Which of the following categories of gasoline has the highest lead susceptibility?

A. Straight run gasoline
B. Platinum reformed gasoline
C. Catalytical cracked gasoline
D. Polymer gasoline
Answer: _________
Question 100:

The main purpose of recycling the byproduct hydrogen gas in the reformer reactor is to

A. Obviate catalyst poisoning
B. Maintain the reaction temperature
C. Sustain the reactor pressure
D. Hydrogenate the feed stock
Answer: _________
Question 101:

Pyrolysis of kerosene or natural gasoline is done to produce mainly the

A. Olefins and aromatics
B. Lighter paraffins
C. Stabilised gasoline
D. Diesel
Answer: _________
Question 102:

Which of the following is desirable in diesel and kerosene but is undersirable in gasoline?

A. Aromatics
B. Mercaptans
C. Paraffins
D. Naphthenic acid
Answer: _________
Question 103:

Performance number of a liquid fuel is related to its

A. Wax content
B. Spontaneous ignition temperature
C. Knocking tendency
D. Sulphur content
Answer: _________
Question 104:

Breathing loss on storage of gasoline occurs due to the

A. Presence of unsaturated air
B. Fluctuation of ambient temperature during day and night
C. Both A & B
D. Neither A nor B
Answer: _________
Question 105:

Octane number of n-heptane is assumed to be

A. 100
B. 0
C. 70
D.
Answer: _________
Question 106:

Absolute vapor pressure of petrofuels is found by Reid bomb which is heated in water bath to 100°F. In Reid apparatus, the ratio of the volume of air chamber to that of the liquid fuel chamber is

A. 1
B. 2
C. 3
D. 4
Answer: _________
Question 107:

Waxes present in petroleum products

A. Can be separated out by distillation
B. Are not soluble in them
C. Crystallise out at low temperature
D. Decrease their viscosity
Answer: _________
Question 108:

Which of the following processes consumes hydrogen?

A. Fluid catalytic cracking
B. Visbreaking
C. Propane deasphalting
D. None of these
Answer: _________
Question 109:

Which is almost absent in crude petroleum?

A. Olefins
B. Mercaptans
C. Naphthenes
D. Cycloparaffins
Answer: _________
Question 110:

Vacuum maintained in the vacuum distillation column in oil refinery is in the range of about __________ mm Hg absolute.

A. 1 to 5
B. 30 to 80
C. 250 to 350
D. 450 to 500
Answer: _________
Question 111:

The yield of straight run LPG from crude oil is about __________ weight percent.

A. 20-25
B. 1-1.5
C. 10-15
D. 0.1-0.2
Answer: _________
Question 112:

Sulphuric acid treatment of petroleum products removes the __________ materials.

A. Gum forming
B. Color forming
C. Asphaltic
D. All of the above
Answer: _________
Question 113:

Petroleum liquid fuels having flash point greater than 66°C is considered as safe during storage and handling. Which of the following has flash point > 66°C ?

A. Naphtha
B. Petrol
C. Kerosene
D. Heavy fuel oil
Answer: _________
Question 114:

Which of the following is the easiest to crack?

A. Paraffins
B. Olefins
C. Naphthenes
D. Aromatics
Answer: _________
Question 115:

Straight run naphtha is converted into high octane number petrol (gasoline) by catalytic

A. Cracking
B. Polymerisation
C. Reforming
D. Isomerisation
Answer: _________
Question 116:

Petrolatum is

A. Same as petroleum ether
B. Petroleum coke
C. A mixture of microcrystalline wax in viscous hydrocarbon liquids
D. None of these
Answer: _________
Question 117:

Petroleum

A. Is optically active
B. Constitutes mainly of olefins
C. Does not contain asphalt
D. Does not contain aromatics
Answer: _________
Question 118:

__________ chloride present in crude petroleum as impurity is the most prolific producer of HCl during distillation.

A. Magnesium
B. Potassium
C. Calcium
D. Sodium
Answer: _________
Question 119:

Crude topping column operates at __________ pressure.

A. Atmospheric
B. 10 atm
C. Vacuum
D. 3 atm
Answer: _________
Question 120:

Mercaptans is represented as (where R and R' are alkyl groups)

A. R-COOH
B. R-S-H
C. R-S-R
D. R-S-R'
Answer: _________
Question 121:

Which of the following is not an important property of fuel oil/furnace oil?

A. Sulphur content
B. Viscosity
C. Aniline point
D. Flash point
Answer: _________
Question 122:

Maximum viscosity of tar/PCM/fuel oil for easy and efficient atomisation in conventional burner is __________ centistokes (or 100 Redwood I seconds).

A. 5
B. 25
C. 50
D. 100
Answer: _________
Question 123:

LPG when brought to atmospheric pressure & temperature will be a

A. Liquid lighter than water
B. Liquid heavier than water
C. Gas lighter than air
D. Gas heavier than air
Answer: _________
Question 124:

Water separometer index (modified) (WSIM) of a petrofuel is the measure of its

A. Emulsification tendency
B. Water separation characteristics
C. Water content
D. Water absorbing capacity from atmosphere
Answer: _________
Question 125:

Which of the following fractions of petroleum contains maximum sulphur?

A. Diesel
B. Gasoline
C. Naphtha
D. Atmospheric residue
Answer: _________
Question 126:

Pick out the additive property of a lube oil out of following.

A. °API gravity
B. Specific gravity
C. Viscosity
D. Flashpoint
Answer: _________
Question 127:

Polymerisation

A. Produces i-octane from cracked gases containing i-butane and butene
B. Causes olefins to combine with each other
C. Causes aromatics to combine with each other
D. Is aimed at producing lubricating oil
Answer: _________
Question 128:

Pour point of a petrofuel is

A. Multiple of 3°F
B. Multiple of 5°F
C. 5°C below the temperature at which oil ceases to flow
D. None of these
Answer: _________
Question 129:

Presence of aromatics in

A. Diesel increases its cetane number
B. Kerosene increases its smoke point
C. Petrol increases its octane number
D. All of the above
Answer: _________
Question 130:

Higher vapour pressure of gasoline indicates

A. Low flash point
B. High breathing loss
C. Both A & B
D. Neither A nor B
Answer: _________
Question 131:

Which of the following processes is used for the production of petroleum coke?

A. Stabilisation
B. Visbreaking
C. Cracking
D. Reforming
Answer: _________
Question 132:

The most important property for a jet fuel is its

A. Viscosity
B. Freezing point
C. Calorific value
D. Flash point
Answer: _________
Question 133:

Mercaptans are added to liquefied petroleum gas (LPG) to

A. Reduce its cost
B. Narrow down its explosion limit
C. Assist in checking its leakage from cylinder
D. Increase its calorific value
Answer: _________
Question 134:

Solution used in Doctor's treatment for the removal of mercaptans is

A. Sodium hydroxide
B. Sodium plumbite
C. Cupric chloride
D. Potassium isobutyrate
Answer: _________
Question 135:

Pick out the wrong statement about the smoking tendency of various hydrocarbon constituents of kerosene.

A. Smoking tendency of hydrocarbons increases in the order : paraffins → isoparaffins → naphthenes → aromatics
B. Smoking tendency of paraffins increases with decrease in its molecular weight
C. Smoking tendency of naphthenes decreases with its increasing molecular weight & also on addition of double bond
D. Smoking tendency of aromatics decreases with increase in its molecular weight
Answer: _________
Question 136:

Name the endothermic reaction out of the following:

A. Catalytic cracking
B. Hydrocracking
C. Dehydrogeneration of naphthene to produce aromatic
D. Catalytic polymerisation
Answer: _________
Question 137:

The conductivity of crude oil-water mixture depends on the

A. PH value
B. Water percentage
C. Temperature
D. All of the above
Answer: _________
Question 138:

Flash point of a liquid petroleum fuel gives an idea about its

A. Volatility
B. Explosion hazards characteristics
C. Nature of boiling point diagram
D. All of the above
Answer: _________
Question 139:

Pressure maintained in the high pressure primary tower of a three stage crude oil distillation system is about __________ kg/cm 2 .

A. 1.5
B. 3
C. 6
D. 12
Answer: _________
Question 140:

Sweetening of petroleum product means the removal of

A. Sulphur & its compounds
B. Water
C. Organic impurities
D. Wax
Answer: _________
Question 141:

Solvent used in the Udex (glycol) extraction process for removal of light aromatics from cracked naphtha is

A. Propane
B. Diethylene glycol
C. Aqueous solution (10% water) of diethylene glycol
D. Methyl ethyl ketone (MEK)
Answer: _________
Question 142:

Carbon/hydrogen ratio (by weight) is maximum (out of following) for

A. Gasoline
B. Kerosene
C. Light gas oil
D. Heavy fuel oil
Answer: _________
Question 143:

Mercaptans are

A. Low boiling sulphur compounds
B. Added in LPG cylinders to detect gas leakage by its smell
C. Undesirable in petrol, as they reduce its octane number
D. All of the above
Answer: _________
Question 144:

Crude oil produced by Indian oil fields are predominantly __________ in nature.

A. Paraffinic
B. Naphthenic
C. Asphaltic
D. Mixed base
Answer: _________
Question 145:

Flash point of atmospheric distillation residue is determined by __________ apparates.

A. Pensky-Martens (closed cup type)
B. Abel
C. Cleveland (open cup type)
D. None of these
Answer: _________
Question 146:

Natural gas recovered along with crude oil from oil wells is called wet natural gas which has a higher __________ compared to the dry natural gas.

A. Unsaturated hydrocarbon content
B. Calorific value
C. Quantity of propane
D. Quantity of butane
Answer: _________
Question 147:

Which of the following is a naphthene?

A. Butene
B. Butadiene
C. Cyclohexane
D. Acetylene
Answer: _________
Question 148:

Which of the following has the lowest flash point of all?

A. Diesel
B. Kerosene
C. Petrol
D. Furnace oil
Answer: _________
Question 149:

Feedstock for the production of biodiesel is

A. Herbal plants
B. Used vegetable oils
C. LSHS
D. Bagasse
Answer: _________
Question 150:

The catalytic cracking of heavier petroleum fraction is done to produce mainly

A. Gasoline
B. Asphalt
C. Diesel oil
D. Tar
Answer: _________
Question 151:

H/C ratio (by weight) for the same number of carbon atoms is the highest in case of

A. Aromatics
B. Paraffins
C. Olefins
D. Naphthenes
Answer: _________
Question 152:

__________ converts n-paraffins to i-paraffins.

A. Alkylation
B. Polymerisation
C. Isomerisation
D. None of these
Answer: _________
Question 153:

C n H 2n is the general formula for

A. Olefins
B. Naphthenes
C. Both A & B
D. Neither A nor B
Answer: _________
Question 154:

Specific gravity of a petroleum product gives an indication of its

A. Degree of refinement
B. Hydrocarbon content type (aromatic or paraffinic)
C. Ease of atomisation
D. Sulphur content
Answer: _________
Question 155:

Which of the following petroleum products contain minimum sulphur?

A. Naphtha
B. Kerosene
C. LSHS
D. Furnace oil
Answer: _________
Question 156:

Refractive index of a petrofuel which is the ratio of velocity of light in air to its velocity in the petrofuel gives an indication if its

A. Molecular weight
B. Aromatics content
C. Both A & B
D. Neither A nor B
Answer: _________
Question 157:

Salt content (measured as sodium chloride) in electrically desalted crude oil comes down to a level of about __________ ptb (pounds per thousand barrel).

A. 0.03
B. 3
C. 35
D. 70
Answer: _________
Question 158:

Aniline point test of an oil qualitatively indicates the __________ content of an oil.

A. Paraffin
B. Olefin
C. Aromatic
D. Naphthene
Answer: _________
Question 159:

Char value of Kerosene is the amount of charred oil deposition on the wick obtained after burning it in a standard wick lamp at a standard rate for 24 hours. Char value of a good quality kerosene should be less than __________ mg/kg of kerosene.

A. 1
B. 20
C. 100
D. 500
Answer: _________
Question 160:

Gasoline yield in catalytic reforming of naphtha may be about __________ percent by weight.

A. 85
B. 65
C. 50
D. 98
Answer: _________
Question 161:

1 centistoke is equal to __________ Redwood I seconds.

A. 1
B. 4.08
C. 0.408
D. 40.8
Answer: _________
Question 162:

The main aim of cracking is to produce

A. Gasoline
B. Lube oil
C. Petrolatum
D. Coke
Answer: _________
Question 163:

Which of the following does not require preheating during storage in the storage tank as well as during atomisation through burners?

A. PCM
B. Tar
C. Light diesel oil
D. Low viscosity furnace oil
Answer: _________
Question 164:

Presence of predominantly large quantity of aromatics (polynuclear) is not desirable in aviation fuel, because it has

A. High pour point and low smoke point
B. Low viscosity index
C. High self-ingnition temperature
D. All of the above
Answer: _________
Question 165:

Which of the following is desirable in petrol (gasoline) but undesirable in kerosene?

A. Paraffins
B. Aromatics
C. Mercaptans
D. Naphthenic acid
Answer: _________
Question 166:

The amount of tetraethyl lead added to improve the octane number of motor gasoline is around __________ c.c per gallon of petrol.

A. 3
B. 300
C. 3000
D. 1000
Answer: _________
Question 167:

True vapour pressure of a petroleum fraction __________ Reid vapour pressure.

A. Is less than
B. Is more than
C. Is same as
D. May be either more or less than
Answer: _________
Question 168:

Octane numbers of motor gasoline used in India and America are respectively

A. 87 & 94
B. 94 & 87
C. 94 & 100
D. 83 & 100
Answer: _________
Question 169:

Which is the most effective catalyst used in catalytic cracking of petroleum products?

A. Iron oxide
B. Nickel
C. Vanadium pentoxide
D. Zeolite
Answer: _________
Question 170:

Glycol added to petrol acts as a/an __________ agent.

A. Anti-knocking
B. Anti-icing
C. Anti-gum forming
D. Dewaxing
Answer: _________
Question 171:

Alkylation

A. Causes olefins to combine with each other
B. Causes olefins to combine with iso-paraffins
C. Converts iso-paraffin into olefin
D. Converts olefin into paraffin
Answer: _________
Question 172:

Which of the following has the highest viscosity of all (at a given temperature)?

A. Naphtha
B. Fuel oil
C. Light diesel oil
D. Petrol
Answer: _________
Question 173:

Gasoline extracted from natural gas (by compression and cooling) is called the __________ gasoline.

A. Polymer
B. Unleaded
C. Casing head
D. Straight run
Answer: _________
Question 174:

Which of the following is used as a solvent in deasphalting of petroleum products?

A. Furfural
B. Propane
C. Methyl ethyl ketone
D. Liquid sulphur dioxide
Answer: _________
Question 175:

True boiling point apparatus is used for the

A. Determination of characterisation factor
B. Evaluation of oil stocks
C. Determination of true vapour pressure
D. None of these
Answer: _________
Question 176:

Raw Kerosene has a smoke point of 15 mm. After it is subjected to dearomatisation by liquid SO 2 extraction (Edeleanu process), its smoke point may become __________ mm.

A. 5
B. 10
C. 25
D. 100
Answer: _________
Question 177:

Smoke point of kerosene expresses its

A. Burning characteristics
B. Luminosity characteristics
C. Aromatic content directly
D. Lamp wick wetting characteristics
Answer: _________
Question 178:

Mercapsol and Unisol processes are meant for the

A. Dearomatisation of kerosene
B. Removal of mercaptans
C. Dewaxing
D. Decoloration
Answer: _________
Question 179:

Older crude petroleum

A. Is light and better
B. Gives more distillates
C. Gives less tar
D. All of the above
Answer: _________
Question 180:

Olefins are

A. Saturated hydrocarbons
B. Unsaturated cyclic compounds (hydrocarbons)
C. Present in substantially good quantity in crude petroleum
D. None of these
Answer: _________
Question 181:

Which of the following is not a sulphur compound present in petroleum ?

A. Thiophenes
B. Mercaptans
C. Sulphones
D. Pyroles
Answer: _________
Question 182:

The doctor's solution comprises of sodium plumbite in

A. Alcohal
B. Water
C. Aqueous caustic soda
D. Soda ash
Answer: _________
Question 183:

Deoiling is the process of removal of oil from wax. It is done by the __________ process.

A. Solvent extraction
B. Sweating
C. Resettling
D. All of the above
Answer: _________
Question 184:

A good lubricant should have high

A. Viscosity index
B. Volatility
C. Pour point
D. None of these
Answer: _________
Question 185:

Name the hydrocarbon having the poorest oxidation stability.

A. Naphthene
B. Olefin
C. Paraffin
D. Aromatics
Answer: _________
Question 186:

Hydrogen content in petroleum products varies from 12 to 15% (by weight). As a result the difference between gross and net heating value of petroleum fuels varies in the range of __________ kcal/kg.

A. 600-750
B. 250-350
C. 1000-1500
D. 2000-2500
Answer: _________
Question 187:

Methyl tertiary butyl ether (MTBE), a high octane (octane no. = 115) gasoline blending component is produced by the simple additive reaction of isobutylene with

A. Methyl alcohol
B. Ethyl alcohol
C. Methane
D. Ethane
Answer: _________
Question 188:

Catalytic desulphurisation process used for sweetening of straight run gasoline and kerosene uses __________ as catalyst.

A. Bauxite
B. Fuller's earth
C. Activated clay
D. All of the above
Answer: _________
Question 189:

Pick out the undesirable property for a solvent meant for dewaxing of lube oil.

A. Complete miscibility with oil
B. High solubility of wax in the solvent
C. Both A & B
D. Neither A nor B
Answer: _________
Question 190:

Catalyst used in isomerisation process is

A. H 2 SO 4
B. H 3 PO 4
C. HF
D. AlCl 3
Answer: _________
Question 191:

Paraffin base crude oil as compared to asphalt base crude gives

A. Higher yield of straight run gasoline
B. Higher octane number gasoline
C. Lower viscosity index lube oil
D. Poorer yield of lube oil
Answer: _________
Question 192:

Straight run petrol as compared to methyl/ethyl alcohol has

A. Lower calorific value
B. Lower octane number
C. Higher specific gravity
D. Higher ignition temperature
Answer: _________
Question 193:

Feed for reforming is generally

A. Naphtha or straight run gasoline
B. Reduced crude
C. Vacuum gas oil
D. Atmospheric gas oil
Answer: _________
Question 194:

Octane number of gasoline produced by two stage fluidised catalytic cracking process is

A. 80
B. 87
C. 92
D. 97
Answer: _________
Question 195:

Which of the following is a non-regenerative fixed bed catalytic reforming process?

A. Hydroforming
B. Thermofer catalytic reforming
C. Platforming
D. Hyperforming
Answer: _________
Question 196:

In case of liquid petrofuels, momentary combustion is observed at its

A. Flash point
B. Preheating temperature corresponding to viscosity of 25 centistokes
C. Flame temperature
D. Fire point
Answer: _________
Question 197:

Main constituent of natural gas is

A. CH 4
B. C 2 H 2
C. C 2 H 4
D. C 2 H 6
Answer: _________
Question 198:

Molecular weight of crude petroleum may be around

A. 50
B. 250
C. 1500
D. 5000
Answer: _________
Question 199:

The characterisation factor of crude petroleum oil is around

A. 3
B. 11
C. 22
D. 28
Answer: _________
Question 200:

With increase in the number of carbon and hydrogen atoms in hydrocarbon molecules, the density of petroleum products

A. Decreases
B. Increases
C. Remains same
D. Unpredictable from the data
Answer: _________
Question 201:

Petroleum deposits are detected by the.

A. Oil seepage at the surface of the earth
B. Measuremet of density, elasticity and magnetic & electric properties of the rock in the crust of the earth
C. Age & nature of rocks inside the crust of the earth
D. All of the above
Answer: _________
Question 202:

Gum formation in stored gasoline is mainly due to the

A. Alkylation of unsaturates
B. Presence of sulphur
C. Oxidation & polymerisation of unsaturates
D. Higher aromatic content
Answer: _________
Question 203:

Which of the following gasolines (unleaded) has the least octane number?

A. Catalytically cracked gasoline
B. Straight run gasoline
C. Catalytically reformed gasoline
D. Polymer gasoline
Answer: _________
Question 204:

Platforming is a __________ process.

A. Moving bed
B. Fluidised bed
C. Non-regenerative & fixed bed
D. Regenerative
Answer: _________
Question 205:

The vacuum maintained in vacuum distillation unit for reduced crude is about __________ mmHg.

A. 1.2
B. 12
C. 120
D. 700
Answer: _________
Question 206:

Liquefied Petroleum Gas (LPG) is mainly a mixture of

A. Propane & butane
B. Methane & ethane
C. High boiling olefins
D. High boiling naphthenes
Answer: _________
Question 207:

LSHS is a type of furnace oil, which

A. Is more viscous than high viscosity furnace oil (HVFO)
B. Stands for low sulphur heavy stock
C. Is an ideal fuel for metallurgical furnaces due to its lower sulphur content (< 1%)
D. All of the above
Answer: _________
Question 208:

__________ base crude oil is also called asphaltic crude.

A. Paraffinic
B. Naphthenic
C. Mixed
D. Aromatic
Answer: _________
Question 209:

A petroleum well is called 'dry', if it contains

A. Very little oil
B. No natural gas
C. Only natural gas
D. All of the above
Answer: _________
Question 210:

Testing of the knocking characteristics of petrofuels is done in a __________ engine.

A. Carnot
B. CFR (Co-operative fuel research)
C. Stirling
D. Diesel
Answer: _________
Question 211:

Removal of light fractions from crude oil is called its

A. Sweetening
B. Dehydration
C. Stabilisation
D. Visbreaking
Answer: _________
Question 212:

Crude oil is pumped by a __________ pump.

A. Gear
B. Centrifugal
C. Screw
D. Reciprocating
Answer: _________
Question 213:

Cetane number of a diesel fuel is the measure of its

A. Ignition delay
B. Smoke point
C. Viscosity
D. Oxidation stability
Answer: _________
Question 214:

Visbreaking

A. Uses natural gas as feed
B. Is carried out at atmospheric pressure
C. Produces fuel oil of lower viscosity
D. Produces gasoline only
Answer: _________
Question 215:

Smoke volatility index is equal to smoke point plus

A. 0.42 × (% distilled at 204°C)
B. 5 mm
C. 0.84 × (% distilled at 204°C)
D. 10 mm approximately
Answer: _________
Question 216:

Antioxidants are added in petrol to

A. Impart colour to it, for easy identification
B. Minimise the gum formation
C. Prevent icing of the carburettor
D. Prevent the lead build up in engines
Answer: _________
Question 217:

Solvent used for dewaxing of petroleum products are

A. Furfural
B. Methyl ethyl ketone (MEK)
C. Propane
D. Both B & C
Answer: _________
Question 218:

Ethyl mercaptan is added to the Doctor negative LPG for facilitating the detection of its leakage (by bad odour) to the extent of about __________ ppm.

A. 1
B. 50
C. 5000
D. 10000
Answer: _________
Question 219:

A typical yield of diesel in straight run distillation of crude oil may be about __________ percent.

A. 8
B. 18
C. 28
D. 35
Answer: _________
Question 220:

A typical yield of kerosene in straight run distillation of crude oil may be about __________ percent.

A. 4
B. 10
C. 18
D. 26
Answer: _________
Question 221:

Naphtha yield in straight run distillation of crude oil may be about __________ percent.

A. 2
B. 6
C. 12
D. 18
Answer: _________
Question 222:

Which of the following processes in oil refinery does not employ 'cracking'?

A. Coking
B. Visbreaking
C. Pyrolysis
D. None of these
Answer: _________
Question 223:

Most widely used solvent for dewaxing is

A. Methyl-ethyl-ketone (MEK)
B. Naphtha
C. Petroleum ether
D. Sodium plumbite
Answer: _________
Question 224:

Which of the following theories of origin of petroleum does not explain the presence of nitrogen & sulphur compounds in crude oil?

A. Modern theory
B. Carbide theory
C. Engler theory
D. All of the above
Answer: _________
Question 225:

Petroleum coke is used mainly in the

A. Discoloration of yellow glycerine
B. Sugar refining
C. Manufacture of carbon electrode
D. Blast furnace for reduction of iron ore
Answer: _________
Question 226:

Maximum use of petroleum coke is in

A. Adsorption refining operation
B. Fuel gas manufacture
C. Carbon electrode manufacture
D. Iron ore reduction
Answer: _________
Question 227:

Aniline point of the diesel is a measure of its __________ content.

A. Aromatic
B. Paraffin
C. Olefin
D. Naphthene
Answer: _________
Question 228:

Concentration of H 2 SO 4 catalyst in alkylation is kept between 90 - 98%, because H 2 SO 4 having concentration

A. Less than 90% promotes polymerisation
B. More than 98% promotes cracking
C. Both A & B
D. Neither A nor B
Answer: _________
Question 229:

Catalyst used in catalytic reforming is

A. Platinum on alumina
B. Nickel
C. Iron
D. Aluminium chloride
Answer: _________
Question 230:

Complete removal of __________ from gasoline is done by Unisol process using caustic soda and methyl alcohol.

A. Waxes
B. Mercaptans
C. Asphalt
D. Diolefins
Answer: _________
Question 231:

The terminology used for the bottom most product from the vacuum crude distillation unit is

A. Residual crude
B. Residuum
C. Reduced crude
D. Petrolatum
Answer: _________
Question 232:

Solvent deoiling process is used for separating oil and soft wax from hard wax. Methyl iso-butyl ketone and methyl ethyl ketone (MEK) are two commonly used deoiling solvents. Use of former as the deoiling solvent has the advantages of the

A. Elimination of solvent drying facility
B. Higher nitration temperature
C. Lower solvent dilution ratio
D. All of the above
Answer: _________
Question 233:

Electrical desalting of crude oil removes the __________ impurities.

A. Oleophilic
B. Oleophobic
C. Both A & B
D. Neither A nor B
Answer: _________
Question 234:

Diesel index.(an alternative index for expressing the quality of diesel) is

A. Determined by using a test engine
B. Not related to aniline point
C. Equal to cetane number plus 3
D. All of the above
Answer: _________
Question 235:

__________ treatment is done for appreciable improvement in viscosity index of lubricating oil.

A. Acid
B. Solvent extraction
C. Alkali
D. Clay
Answer: _________
Question 236:

Smoke point of kerosene is the

A. Time after which smoking starts on burning
B. Temperature at which smoking starts
C. Maximum height of flame (in mm) without causing smoking, when burnt in a standard lamp
D. None of these
Answer: _________
Question 237:

The colour of gasoline is an indication of its

A. Octane number
B. Lead susceptibility
C. Gum forming tendency & thoroughness of refining
D. None of these
Answer: _________
Question 238:

Boiling range of motor gasoline is an indication of the

A. Case of starting
B. Rate of acceleration
C. Vapour locking tendency
D. All of the above
Answer: _________
Question 239:

In solutizer sweetening process, solutizer solution used is

A. Methanol in Unisol process
B. Naphthenic acid in Mercapsol process
C. Both A & B
D. Neither A nor B
Answer: _________
Question 240:

Higher pressure in the reforming reactor

A. Increases coke formation
B. Increases the rate of reaction
C. Produces high octane number gasoline
D. None of these
Answer: _________
Question 241:

Bottom product of atmospheric pressure crude oil distillation column is termed as

A. Reduced crude
B. Heavy ends
C. Asphalt
D. Residuum
Answer: _________
Question 242:

For gasoline, the flash point (<50°C) is determined by the

A. Abel apparatus
B. Pensky-Marten's apparatus
C. Saybolt chromometer
D. None of these
Answer: _________
Question 243:

Vacuum maintained in the vacuum distillation tower of the crude distillation plant is about __________ mm Hg (absolute).

A. 5-10
B. 30-80
C. 150-250
D. 350-400
Answer: _________
Question 244:

Octane number (unleaded) of reformed gasoline may be upto

A. 60
B. 70
C. 80
D. 90
Answer: _________
Question 245:

The reservoir rock containing petroleum has

A. Low porosity
B. High permeability
C. High porosity
D. Both B and C
Answer: _________
Question 246:

Sour crude means the __________ bearing crude.

A. Asphalt
B. Sulphur compounds
C. Wax
D. Nitrogen compounds
Answer: _________
Question 247:

Penetration test determines the __________ of the grease.

A. Stiffness
B. Lubricating properties (e.g. oilness)
C. Service temperature
D. Variation in viscosity with temperature
Answer: _________
Question 248:

Isomerisation converts the __________ tot-paraffins.

A. Paraffins
B. Olefins
C. Naphthenes
D. None of these
Answer: _________
Question 249:

Which of the following additives improves the cetane number of diesel?

A. Amyl nitrate
B. Ethyl mercaptan
C. Napthenic acid
D. Tetra ethyl lead
Answer: _________
Question 250:

Which of the following is an additive used for improving the cetane number of diesel?

A. Tetraethyl lead
B. Tetramethyllead
C. Ethyl nitrate or acetone
D. None of these
Answer: _________
Question 251:

Catalyst used in alkylation process is

A. Sulphuric acid
B. Nickel
C. Silica gel
D. Alumina
Answer: _________
Question 252:

Molecular weight of petrol may be about

A. 40-60
B. 100-130
C. 250-300
D. 350-400
Answer: _________
Question 253:

Tetraethyl lead is added to the petrol to increase its octane number, because its octane number is

A. More than 100
B. Round about 100
C. Between 50 and 100
D. Less than 25
Answer: _________
Question 254:

Maximum sulphur percentage in low sulphur heavy stock (LSHS) furnace oil is about

A. 0.1
B. 1
C. 2.5
D. 3.5
Answer: _________
Question 255:

Which one is used to determine the colour of petroleum products?

A. Colour comparator
B. Saybolt chromometer
C. Cleveland apparatus
D. None of these
Answer: _________
Question 256:

Cracking is

A. An exothermic reaction
B. An endothermic reaction
C. Favoured at very low temperature
D. None of these
Answer: _________
Question 257:

During electrical desalting of crude oil, the electrical conductivity of a mixture of crude oil and water (which ranges between 3 to 8% water) __________ with increase in the amount of water.

A. Decreases
B. Increases
C. Remains unchanged
D. Decreases linearly
Answer: _________
Question 258:

Aromatics are desired constituents of

A. Lubricating oil
B. Diesel
C. Kerosene
D. Petrol
Answer: _________
Question 259:

Catalytic cracking compared to thermal cracking of residue of vacuum distillation of crude oil

A. Gives higher yield of petrol
B. Lower octane number of petrol
C. Higher sulphur content in the product
D. Higher gum forming material in petrol
Answer: _________
Question 260:

The main use of heavy gas oil produced by the vacuum distillation unit is as a

A. Blending component for kerosene
B. Blending component for petrol
C. Feedstock for fluid catalytic cracking unit
D. None of these
Answer: _________
Question 261:

__________ determination is not a very significant and important test for gasoline.

A. Gum & sulphur content
B. Viscosity
C. Octane number
D. Reid vapor pressure
Answer: _________
Question 262:

Catalyst used in the catalytic cracking is

A. Silica-alumina
B. Silica gel
C. Vanadium pentoxide
D. Nickel
Answer: _________
Question 263:

Naphthenic acid is a/an __________ compound.

A. Sulphur
B. Nitrogen
C. Oxygen
D. None of these
Answer: _________
Question 264:

Natural gasoline is produced

A. From oil wells
B. In oil refineries
C. By natural gas stripping
D. None of these
Answer: _________
Question 265:

Pour point and freezing point is equal for

A. Petrol
B. Diesel
C. Water
D. Crude petroleum
Answer: _________
Question 266:

The general formula of naphthenes is

A. C n H 2n + 2
B. C n H 2n - 6 (where, n ≥ 6)
C. C n H n - 4
D. Same as that for olefins i.e. C n H 2n
Answer: _________
Question 267:

Most commonly used crude heater before the fractionation tower in a refinery is the __________ heater.

A. Electric immersion
B. Pipestill
C. Steam coil
D. None of these
Answer: _________
Question 268:

Casing head gasoline is the liquid

A. Butane
B. Propane
C. Natural gas
D. Gasoline separated from wet natural gas by compression
Answer: _________
Question 269:

Which of the following is the most widely used cracking process in oil refineries?

A. Dubbs process
B. T.C.C. moving bed process
C. Fluidised bed catalytic cracking process
D. Houdry's fixed bed process
Answer: _________
Question 270:

Which of the following tests is not done for transformer oil?

A. Flash point and acid value
B. Aniline point
C. Dielectric strength
D. Copper strip corrosion test
Answer: _________
Question 271:

Aniline point is the temperature at which

A. Equal weight of diesel & the aniline are completely miscible
B. Equal weight of aniline & the test sample are completely miscible
C. Equal volume of aniline & the test sample are completely miscible
D. Aniline vaporises
Answer: _________
Question 272:

Choose the correct statement regarding thermal cracking.

A. Moderate changes in operating temperature does not change the depth of cracking
B. Increased residence time results in the decreased severity of cracking
C. At low pressure, the yield of lighter hydrocarbons are more
D. Greater depth of cracking gives lower octane number gasoline
Answer: _________
Question 273:

Solvent used in Edeleanu process is

A. Furfural
B. Propane
C. Liquid SO 2
D. Phenol
Answer: _________
Question 274:

Which of the following fractions of a crude oil will have the maximum gravity API (i.e. °API) ?

A. Diesel
B. Gasoline
C. Atmospheric gas oil
D. Vacuum gas oil
Answer: _________
Question 275:

The solvent used in Barisol dewaxing process is

A. Hexane
B. Furfural
C. Benzol and ethylene dichloride
D. Methyl ethyl ketone (MEK)
Answer: _________
Question 276:

Pressure & temperature maintained in catalytic cracking is about

A. 2atm & 500°C
B. 10atm & 500°C
C. 30atm & 200°C
D. 50atm. & 750°C
Answer: _________
Question 277:

In catalytic cracking, the

A. Gasoline obtained has a very low octane number
B. Pressure & temperature is very high
C. Gasoline obtained has very high aromatic content
D. Gasoline obtained has very high amount of gum forming compounds
Answer: _________
Question 278:

Solvent used in the deasphalting process is

A. Furfurol
B. Phenol
C. Propane
D. Hexane
Answer: _________
Question 279:

The average boiling point of aviation turbine fuel is closest to that of

A. Lubricating oils
B. LPG
C. Diesel
D. Kerosene
Answer: _________
Question 280:

Aniline point is a property of the

A. Diesel
B. LPG
C. Naphtha
D. Gasoline
Answer: _________
Question 281:

Though increased pressure has a retarding effect on cracking reaction, yet in actual process, a positive pressure of 10 - 15 kgf/cm 2 is maintained during cracking mainly to

A. Increase the yield of light distillates
B. Suppress coke formation
C. Enhance the octane number of gasoline
D. Reduce gum content in gasoline
Answer: _________
Question 282:

Which of the following contains maximum sulphur?

A. Diesel
B. Petrol
C. Kerosene
D. Fuel oil
Answer: _________
Question 283:

Tanks used for the storage of petroleum products (which are inflammable) should be painted with a __________ paint.

A. Black
B. White
C. Red
D. Yellow
Answer: _________
Question 284:

__________ is not an important refinery process for upgrading the quality of lubricating oil.

A. Deoiling
B. Solvent refinning
C. Clay treatment
D. Hydrotreatment
Answer: _________
Question 285:

Smoke point of a test sample of kerosene is found to be 15 mm. On removal of __________ from it, the smoke point rises to 25 mm.

A. N-paraffins
B. Olefins
C. Aromatics
D. None of these
Answer: _________
Question 286:

__________ test is done to find out the softening point of bitumen.

A. Impact
B. Ball and ring
C. Flame
D. Viscosity
Answer: _________
Question 287:

Which is an anticing compound?

A. Amyl nitrate
B. Alcohals
C. Mercaptans
D. Pyridine
Answer: _________
Question 288:

In the atmospheric pressure crude distillation, the content of __________ from lighter fraction to heavier ones.

A. Sulphur increases
B. Sulphur decreases
C. Nitrogen decreases
D. None of these
Answer: _________
Question 289:

Naphthenic acid is represented by

A. C n H 2n+2 O 2
B. C n H 2n-2 O 2
C. C n H 2n+2 O 2 (n ≥ 6)
D. C n H 2n+6 O 2 (n ≤ 6)
Answer: _________
Question 290:

Hydrocracking employs

A. High pressure & temperature
B. Low pressure & temperature
C. High pressure and low temperature
D. High temperature and low pressure
Answer: _________
Question 291:

Pick out the correct statement.

A. Paraffins have higher octane number than corresponding iso-paraffin
B. Paraffins have lower smoke point than aromatics
C. Suitability of kerosene as a fuel & as an illuminant may be determined by char value test
D. Aviation fuel should have very high cloud point
Answer: _________
Question 292:

Solvent used in duo-sol extraction for lube oil upgradation is a mixture of

A. Propane & phenol-cresol mixture
B. Methyl ethyl ketone & glycol
C. Phenol & furfural
D. Propane & liquid sulphur dioxide
Answer: _________
Question 293:

In sweetening process, solutizer agent used with caustic alkali is

A. Potassium isobutyrate
B. Sodium plumbite
C. Methanol
D. Phenol
Answer: _________
Question 294:

In catalytic alkylation, higher iso-butane to olefin ratio gives

A. Low final boiling point product
B. Higher yield
C. Both A & B
D. Neither A nor B
Answer: _________
Question 295:

Aromatics have the highes __________ of all the hydrocarbons of same carbon atoms.

A. Smoke point
B. Octane number
C. Cetane number
D. Viscosity
Answer: _________
Question 296:

Thermofer catalytic cracking process is a __________ process.

A. Fixed bed
B. Moving bed
C. Fluidised bed
D. Non-catalytic
Answer: _________
Question 297:

The order of preference for feedstock to a catalytic reformer is

A. Catalytic naphtha - coking naphtha - virgin naphtha
B. Coking naphtha - virgin naphtha - catalytic naphtha
C. Virgin naphtha - catalytic naphtha - coking naphtha
D. Virgin naphtha - coking naphtha - catalytic naphtha
Answer: _________
Question 298:

Iso-octane is used as a reference substance in the definition of octane number and it is assigned an octane number value of 100. Iso-octance is chemically known as

A. α-methyl naphthalene
B. 2-2-4 tri methyl pentane
C. 1, 3 butadiene
D. Tetra methyl ethylene
Answer: _________
Question 299:

Flash point of an oil gives an idea of the

A. Nature of boiling point diagram of the system
B. Amount of low boiling fraction present
C. Explosion hazards
D. All of the above
Answer: _________
Question 300:

Flash point of an oil is determined by the

A. Pensky Martens apparatus
B. Ramsbottom apparatus
C. Saybolt viscometer
D. Conradson apparatus
Answer: _________
Question 301:

Cetane number of high speed diesel must be?

A. 30
B. 45
C. 75
D. 95
Answer: _________
Question 302:

Good quality kerosene should have

A. Low smoke point
B. High smoke point
C. High aromatics content
D. Low paraffins content
Answer: _________
Question 303:

Crude oil is transported inland from oil field to refineries, mainly by the

A. Road tankers
B. Rail tankers
C. Underground pipelines
D. None of these
Answer: _________
Question 304:

Fuel oil is subjected to visbreaking to reduce its

A. Pour point
B. Viscosity
C. Pressure drop on pumping
D. All of the above
Answer: _________
Question 305:

The most suitable solvent for deasphalting vacuum residue is

A. Propane
B. Methyl ethyl ketone
C. Doctor's solution
D. Methanol amine
Answer: _________
Question 306:

Deoiling of wax is done by its

A. Heating
B. Cooling
C. Solvent extraction
D. Both B & C
Answer: _________
Question 307:

The proper arrangement of the petroleum fractions in order of their boiling points is

A. Lubricating oil > diesel > petrol > LPG
B. Lubricating oil > petrol > diesel > LPG
C. Petrol > lubricating oil > diesel > LPG
D. Petrol > diesel > LPG > lubricating oil
Answer: _________
Question 308:

Diesel index is defined as

A. (°API) × (Aniline Point, °F)/100
B. (°API) × (Aniline Point, °C)/100
C. (°API) × (100)/Aniline Point, °F
D. (°API) × (100)/Aniline Point, °C
Answer: _________
Question 309:

Furfural solvent extraction is used for upgrading (by dissolving aromatics)

A. Naphtha
B. Lubricating oils
C. Wax
D. Cracking feedstock
Answer: _________
Question 310:

Dearomatisation of kerosene (by liquid sulphur dioxide extraction) is done to

A. Increase its smoke point
B. Improve its oxidation stability
C. Decrease the breathing loss
D. None of these
Answer: _________
Question 311:

Percentage of straight run gasoline in a typical crude oil may be around

A. 6
B. 18
C. 38
D. 52
Answer: _________
Question 312:

Which of the following has the lowest viscosity (at a given temperature) of all?

A. Naphtha
B. Kerosene
C. Diesel
D. Lube oil
Answer: _________
Question 313:

Hydrofining is the most recent and effective method for the

A. Removal of sulphur
B. Improvement of smoke point
C. Reduction of breathing loss
D. Improvement of viscosity index
Answer: _________
Question 314:

Which is the most desirable component of a good quality kerosene?

A. I-paraffins
B. Aromatics
C. N-paraffins
D. Naphthenes
Answer: _________
Question 315:

High aniline point of diesel indicates that, it

A. Is highly aromatic
B. Has a large ignition delay
C. Is highly paraffinic
D. Has a low diesel index
Answer: _________
Question 316:

Catalyst used in the isomerisation is

A. Aluminium chloride
B. Alumina
C. Nickel
D. Phosphoric acid
Answer: _________
Question 317:

Pick out the correct statement pertaining to catalytic cracking.

A. With increase in the reactor pressure, octane number of gasoline decreases
B. With increase in the reactor temperature, gasoline yield decreases for a given conversion
C. Percentage conversion increases with increase in the catalyst to oil ratio
D. All of the above
Answer: _________
Question 318:

Which of the following is the most important property for a jet fuel?

A. Cloud point
B. Pour point
C. Colour
D. Freezing point
Answer: _________
Question 319:

Which of the following is the most suitable feed for platforming process (reforming)?

A. Olefinic hydrocarbon
B. Naphtha
C. Fuel oil
D. Atmospheric residue
Answer: _________
Question 320:

Liquefied Petroleum Gas (LPG) in domestic use cylinders is in the liquid form. The density of LPG in liquid form is about __________ of that of water (i.e. 1 gm/c.c).

A. One fourth
B. One third
C. Half
D. One eighth
Answer: _________
Question 321:

The coking process normally mostly used in Indian oil refineries is the __________ coking process.

A. Delayed
B. Flexi
C. Fluid
D. Contact
Answer: _________
Question 322:

Equal volumes of aniline and diesel oil when mixed at room temperature (during summer) was found to be completely mis-cible. It means that the aniline point of the diesel is __________ the room temperature.

A. More than
B. Less than
C. Same as
D. Either more or less depends on the room temperature
Answer: _________
Question 323:

The characterisation factor of a crude oil is calculated as 12.5. It means that
it is

A. Paraffinic
B. Naphthenic
C. Intermediate
D. None of these
Answer: _________

Answer Key

1: B
2: C, E, L, O, Q, W, \, ^, c
3: C
4: B
5: D
6: C
7: A
8: B
9: A
10: C
11: B
12: A
13: B
14: C
15: A
16: B
17: C
18: A
Solution: In the electrical desalting process of crude oil, the main objective is to remove salts and other impurities by mixing the crude oil with water and applying an electric field. The typical operating conditions for this process involve maintaining a pressure of 10 kg/cm 2 and a temperature of 120°C . These conditions are optimal for the efficient separation of impurities from the crude oil. Therefore, Option A: 10 and 120 is the correct answer.
19: B
20: B
21: A
22: D
23: C
24: B
25: D
26: D
27: C
28: B
Solution: In petroleum refinery engineering, the research octane number (RON) refers to high octane number motor fuels (Option B). The research octane number (RON) is a measure of the anti-knock properties of motor fuels. Higher RON values indicate better resistance to knocking or detonation in spark-ignition engines. Fuels with high RON values are desirable for use in high-performance engines or engines with high compression ratios, as they help prevent knocking and improve engine efficiency. Therefore, the correct option is Option B: High octane number motor fuels .
29: C, E
30: D
31: A
32: A
33: D
34: A
35: B
36: C
37: B
38: B
39: D
40: B
41: A
42: A
43: A
44: C
45: A
46: B
47: C
48: A
49: D
50: A
51: D
52: B
53: B
54: A
55: B
Solution: In petroleum, the constituents responsible for ash formation are typically organometallic compounds . These compounds contain both organic (carbon-based) and metal components. During the refining process, when petroleum is subjected to high temperatures and pressure, these organometallic compounds can decompose and leave behind solid residues, forming ash. Therefore, in this context, the correct option is Option B: Organometallic compounds .
56: C
57: A
58: A
59: B
60: B
61: B
62: B
63: A
64: A
Solution: The cetane number of diesel is a measure of its ignition quality or how easily the fuel ignites under compression in a diesel engine. For diesel fuel used in trucks, the cetane number is typically around 50 , which ensures efficient combustion and engine performance. A higher cetane number indicates better ignition properties, leading to smoother engine operation and reduced emissions. Therefore, Option A: 50 is the correct answer.
65: C
66: A
67: B
68: D
69: C
70: D
71: B
72: A
73: A
74: C
75: C
76: A
77: B
78: D
79: B
80: C
81: B
Solution: The correct answer is B: Vacuum residue . Here's why: Coking is a process that uses heat to break down large, heavy hydrocarbon molecules into smaller, lighter ones and solid carbon (coke). Vacuum residue is the heaviest fraction remaining after vacuum distillation of crude oil. It contains the largest and most complex molecules , making it the most suitable feedstock for coking. Let's look at the other options: Naphtha, Light gas oil and Diesel are all relatively lighter fractions with smaller molecules . They do not contain enough of the heavy components required for efficient coke production. These fractions are generally used as gasoline, diesel fuel, and heating oil. Therefore, vacuum residue is the most ideal feed for coking because it maximizes coke production.
82: A
83: C
84: A
85: D
Solution: In petroleum refinery engineering, the water content in crude oil as it comes out of the oil well may be as high as 25 percent (Option D). Crude oil extracted from oil wells often contains various impurities, including water, sediments, and gases. The water content in crude oil can vary depending on factors such as the geological formation of the oil reservoir and the methods used for oil extraction. In some cases, crude oil may contain significant amounts of water, up to 25 percent or more, which needs to be separated and removed during the refining process. Therefore, the correct option is Option D: 25 .
86: C
87: B
88: C
89: A
90: C
91: B
92: A
93: C
94: C
95: A
96: A
97: A
98: B
Solution: The grading of paraffin waxes is primarily based on their melting point . The melting point is a critical parameter because it determines the temperature at which the wax transitions from a solid to a liquid state. Different applications require paraffin waxes with specific melting points to ensure proper performance. Therefore, Option B: Melting point is the correct answer.
99: A
100: C
101: A
102: A
103: B
104: B
105: B
106: D
107: C
108: A
109: B
Solution: In petroleum refinery engineering, mercaptans are almost absent in crude petroleum (Option B). Mercaptans, also known as thiols, are sulfur-containing organic compounds with the general formula R-SH, where R represents an organic group. While mercaptans can be present in refined petroleum products as contaminants, they are typically absent or present in very low concentrations in crude petroleum. Therefore, the correct option is Option B: Mercaptans .
110: B
111: B
112: D
113: D
114: A
115: C
116: C
117: A
118: A
119: A
120: B
121: C
122: B
123: D
124: B
125: D
126: A
127: B
128: C
129: C
130: D
131: C
132: B
133: C
134: B
135: B
136: B
Solution: Option A: Catalytic cracking - Catalytic cracking is a process where large hydrocarbon molecules are broken down into smaller ones using a catalyst. This process is typically exothermic, meaning it releases heat as the molecules are broken apart. Option B: Hydrocracking - Hydrocracking is a process similar to catalytic cracking, but it involves the addition of hydrogen gas under high temperature and pressure. This process requires the input of external heat energy to drive the cracking process, making it endothermic. Option C: Dehydrogenation of naphthene to produce aromatic - Dehydrogenation reactions involve the removal of hydrogen atoms from hydrocarbon molecules to produce unsaturated compounds. While these reactions can occur with or without external heat, they are generally considered to be slightly endothermic. Option D: Catalytic polymerisation - Catalytic polymerization involves the joining together of smaller hydrocarbon molecules to form larger ones, typically under the influence of a catalyst. This process is usually exothermic, as the bonds formed release energy. Conclusion: While all the options involve important processes in petroleum refining, the only one classified as endothermic is Option B: Hydrocracking. In hydrocracking, the input of external heat energy is necessary to drive the cracking process. Therefore, the correct answer is Option B.
137: D
138: D
139: B
140: A
141: C
142: A
143: D
144: C
145: C
146: B
147: C
148: C
149: B
150: C
151: D
152: C
153: C
154: B
155: A
156: C
157: B
158: C
Solution: Definition: The aniline point of an oil is the minimum temperature at which the oil is completely miscible with an equal volume of aniline. Purpose of test: It is used as a qualitative measure of the aromatic content in petroleum oils. Reason: Aromatic hydrocarbons mix more readily with aniline than paraffinic hydrocarbons, resulting in a lower aniline point for oils with higher aromatic content. Conversely, oils rich in paraffins have higher aniline points. Conclusion: The aniline point test gives an indication of the aromatic content of an oil — lower aniline point means higher aromatic content, and higher aniline point means lower aromatic content.
159: B
160: A
161: B
162: A
163: C
164: D
Solution: The presence of predominantly large quantities of aromatics (polynuclear) in aviation fuel is undesirable due to several reasons, leading to various negative effects on the fuel's properties and performance. These include: High pour point: Aromatics can contribute to higher pour points, which can lead to poor flow characteristics at low temperatures, affecting the fuel's ability to flow through fuel systems and into engines during cold weather conditions. Low smoke point: Aromatics tend to have lower smoke points, which can result in increased smoke production during combustion. This can lead to reduced visibility, increased emissions, and potential operational issues. Low viscosity index: Aromatics can lower the viscosity index of the fuel, which affects its ability to lubricate and provide proper protection to engine components. High self-ignition temperature: Aromatics can contribute to a higher self-ignition temperature, making the fuel more prone to autoignition, especially at high temperatures and pressures, which can lead to engine knocking and other performance problems. Considering these negative effects, the correct answer is Option D: All of the above , as all of these factors contribute to the undesirability of predominantly large quantities of aromatics in aviation fuel.
165: B
166: A
167: D
168: A
169: D
170: B
171: B
172: B
173: C
Solution: In petroleum refinery engineering, gasoline extracted from natural gas by compression and cooling is referred to as casing head gasoline (Option C). Casing head gasoline is a type of natural gasoline obtained during the initial processing of natural gas. It is typically a mixture of hydrocarbons with relatively low octane ratings compared to other types of gasoline. Casing head gasoline is used as a fuel or as a feedstock in various chemical processes. Therefore, the correct option is Option C: Casing head .
174: B
175: D
176: C
177: A
178: B
179: D
Solution: Older crude petroleum is generally considered light and better because it has undergone natural refining processes over time. It typically gives more distillates , which are the valuable fractions obtained during refining. Additionally, older crude gives less tar , making it more desirable for refining purposes. Therefore, all the statements are true, making Option D: All of the above the correct answer.
180: B
Solution: In petroleum refinery engineering, olefins are unsaturated cyclic compounds (hydrocarbons) (Option B). Olefins, also known as alkenes, are a class of hydrocarbons containing at least one carbon-carbon double bond. They are unsaturated compounds because they contain fewer hydrogen atoms than the corresponding saturated hydrocarbons. Olefins are widely used in the petrochemical industry as feedstocks for producing various chemicals, including plastics, solvents, and synthetic fibers. Therefore, the correct option is Option B: Unsaturated cyclic compounds (hydrocarbons) .
181: D
182: C
183: D
184: A
185: B
Solution: In petroleum refinery engineering, aromatics are the hydrocarbons having the poorest oxidation stability. Aromatics, such as benzene, toluene, and xylene, contain one or more benzene rings in their molecular structure. These compounds are highly reactive and prone to oxidation, which can lead to the formation of harmful by-products and degradation of the petroleum product's quality over time. Therefore, the correct option is Option D: Aromatics .
186: A
187: A
188: D
189: C
190: D
191: A
192: B
193: A
194: D
195: C
196: A
197: A
198: C
199: B
200: B
201: D
202: B
203: B
204: C
205: C
206: A
207: D
208: B
209: C
210: B
211: C
212: B
213: A
214: C
215: A
216: B
217: C
218: B
219: A
220: B
221: B
222: D
223: A
224: B
225: C
226: C
227: A
Solution: The aniline point of diesel is a measure of its aromatic content. It is a test used in the petroleum industry to determine the solubility and aromatic hydrocarbon content of diesel fuel. The aniline point is the temperature at which an equal volume of aniline and diesel fuel are completely miscible (able to mix uniformly). It indicates the presence and quantity of aromatic hydrocarbons in the diesel fuel. Therefore, the correct answer is Option A: Aromatic . The aniline point is a measure of the aromatic content in diesel fuel. Options B, C, and D refer to different types of hydrocarbons but are not specifically related to the aniline point test for diesel.
228: C
229: A
230: B
231: B
232: D
233: B
234: C
235: B
236: C
Solution: In petroleum refinery engineering, the smoke point of kerosene refers to the maximum height of flame (in mm) without causing smoking, when burnt in a standard lamp (Option C). The smoke point is an important parameter that indicates the quality of kerosene or other liquid fuels. It represents the maximum temperature at which the fuel can be burned without producing visible smoke. When the flame exceeds this height, incomplete combustion occurs, resulting in the emission of smoke. Therefore, the correct option is Option C: Maximum height of flame (in mm) without causing smoking, when burnt in a standard lamp .
237: C
238: B
239: C
240: D
241: A
242: A
Solution: The Abel apparatus is another commonly used instrument for determining the flash point of volatile liquids. It operates by gradually heating a sample of the liquid in a closed vessel and passing a small flame over the surface of the liquid at regular intervals. The flash point is the lowest temperature at which the vapors of the liquid ignite momentarily when exposed to the flame under specified test conditions. Therefore, the correct option is Option A: Abel apparatus .
243: B
244: D
245: D
246: B
247: A
248: A
249: D
Solution: Option A: Amyl nitrate - Amyl nitrate is not commonly used as an additive to improve the cetane number of diesel. It is more commonly associated with other applications, such as as a vasodilator or in the production of explosives. Option B: Ethyl mercaptan - Ethyl mercaptan is a compound used primarily as an odorant in natural gas and propane. It is not used to improve the cetane number of diesel fuel. Option C: Napthenic acid - Napthenic acid is a type of organic acid found in petroleum. While it is sometimes used as an additive in lubricating oils, it is not used to improve the cetane number of diesel. Option D: Tetra ethyl lead - Tetra ethyl lead is the correct additive that improves the cetane number of diesel fuel. It enhances the ignition quality of diesel, leading to smoother engine operation and lower emissions. Conclusion: Among the options provided, Option D: Tetra ethyl lead is the correct additive used to improve the cetane number of diesel fuel. Therefore, the correct answer is Option D .
250: A
Solution: In petroleum refinery engineering, the additive used for improving the cetane number of diesel is Tetraethyl lead (Option A). The cetane number is a measure of the ignition quality of diesel fuel. Higher cetane numbers indicate better ignition quality, leading to smoother engine operation, reduced noise, and lower emissions. Tetraethyl lead is one of the additives used to increase the cetane number of diesel fuel by improving its combustion characteristics. Therefore, the correct option is Option A: Tetraethyl lead .
251: A
252: B
253: A
254: B
255: B
Solution: In petroleum refinery engineering, the Saybolt chromometer is used to determine the color of petroleum products. The Saybolt chromometer measures the color of petroleum products by comparing them to standard color discs under standardized lighting conditions. It provides a numerical value representing the color, which is used to assess the quality and purity of the petroleum product. Therefore, the correct option is Option B: Saybolt chromometer .
256: B
257: B
258: D
259: A
260: C
261: B
262: A
263: C
264: C
265: C
266: D
267: B
268: D
Solution: In petroleum refinery engineering, casing head gasoline is the liquid gasoline separated from wet natural gas by compression (Option D). Casing head gasoline is obtained during the initial processing of natural gas. When natural gas is extracted from underground reservoirs, it often contains liquid hydrocarbons, including gasoline, which are separated from the gas stream by compression. This gasoline, known as casing head gasoline, is typically a mixture of hydrocarbons and is used as a fuel or as a feedstock in various chemical processes. Therefore, the correct option is Option D: Gasoline separated from wet natural gas by compression .
269: C
270: B
271: C
272: D
273: C
274: B
Solution: In petroleum refinery engineering, gasoline fraction of a crude oil will have the maximum gravity API (°API). The gravity API (°API) is a measure of the density of petroleum liquids compared to water. Higher API gravity values indicate lighter and less dense liquids. Gasoline is typically one of the lightest fractions obtained from crude oil refining processes, and therefore, it tends to have the highest API gravity among the options provided. Therefore, the correct option is Option B: Gasoline .
275: C
276: A
277: C
278: C
279: D
280: C
Solution: Option A: Diesel - Diesel is a petroleum distillate commonly used as fuel in compression-ignition engines. The aniline point of diesel is typically higher compared to naphtha or gasoline. Diesel contains fewer aromatic hydrocarbons compared to naphtha, which results in a higher aniline point. Option B: LPG - LPG (liquefied petroleum gas) consists primarily of propane and butane. It is not typically tested for aniline point as it is composed mainly of aliphatic hydrocarbons, which have lower aromatic content compared to naphtha. Option C: Naphtha - Naphtha is a petroleum fraction containing a mixture of hydrocarbons, including both aliphatic and aromatic compounds. The aniline point of naphtha is determined by the temperature at which it becomes completely miscible with an equal volume of aniline. Naphtha contains a significant amount of aromatic hydrocarbons, which contribute to its aniline point. Option D: Gasoline - Gasoline, like naphtha, is a petroleum fraction containing a mixture of hydrocarbons. It typically contains a higher proportion of light hydrocarbons and fewer aromatics compared to naphtha. Gasoline tends to have a lower aniline point compared to naphtha due to its lower aromatic content. Conclusion: Among the options provided, Option C: Naphtha is the petroleum product commonly associated with the aniline point. Naphtha contains a significant amount of aromatic hydrocarbons, which influence its aniline point. Therefore, the correct answer is Option C: Naphtha .
281: B
282: D
283: B
284: A
285: C
286: B
287: B
288: A
289: B
290: A
291: B
292: A
293: A
294: A
295: B
296: C
Solution: In petroleum refinery engineering, the Thermofer catalytic cracking process is a fluidised bed process (Option C). Fluidised bed catalytic cracking processes involve the use of a fluidised catalyst bed where the catalyst particles are suspended and mixed with the hydrocarbon feedstock. This allows for efficient mixing and contact between the catalyst and the feedstock, promoting the cracking reactions to produce desired products such as gasoline, diesel, and other valuable hydrocarbons. Therefore, the correct option is Option C: Fluidised bed .
297: D
Solution: In petroleum refinery engineering, the order of preference for feedstock to a catalytic reformer is Virgin naphtha - coking naphtha - catalytic naphtha (Option D). Virgin naphtha: Virgin naphtha refers to the naphtha fraction obtained directly from the crude oil distillation process. It typically contains fewer impurities and is considered the highest quality naphtha for catalytic reforming. Coking naphtha: Coking naphtha is obtained as a by-product from the thermal cracking or coking process. It may contain higher levels of impurities and may have a lower quality compared to virgin naphtha. Catalytic naphtha: Catalytic naphtha is obtained from the catalytic reforming process itself. It is typically of lower quality compared to virgin naphtha and may contain more impurities. Therefore, the correct order of preference is Virgin naphtha - coking naphtha - catalytic naphtha , making Option D the correct answer.
298: B
299: A
300: A
301: B
302: B
303: C
304: D
305: B
306: D
307: A
308: A
309: B
310: B
311: D
312: A
313: A
314: C
315: C
316: A
317: D
318: D
319: A
320: C
321: A
322: C
323: A